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Is Glass a liquid ?
One can occasionally hear in art history courses the erroneous
idea that "Because glass is a liquid, it flows very slowing. Evidence of this can be
seen in Medieval stained glass windows which are thicker at the bottom than they are at
the top." This is not true, and the notion behind it is unfounded. Glass does not flow to a measurable extent at room temperature even over very long
periods of time. Thickness at the bottom, the sides and the top of the segments that make
an entire Medieval stained glass window happened by chance in the cutting, and as a result
of the manufacture of the disk from which they were cut. The term "viscosity" is usually applied to liquids, and means, in a
qualitative sense, the resistance that a liquid offers to flow. A liquid with a high
viscosity such as molasses flows slowly, compared with water with a lower viscosity which
flows much faster. Viscosities are expressed in a unit called the poise. The viscosity of water at room
temperature is .010 poise; that of SAE30 motor oil is about 1.0 poise. The viscosity of
most glass at room temperature is theoretically about As the temperature of glass increases, the inflexible molecular network breaks down
into smaller units. Viscosity drops to about 107 poises and may start to deform
under its own weight. At higher temperatures, viscosity drops to 103-4 poises
when the glass will flow into a mold, or can be blown with ease. When heated to very high temperatures, the viscosities of glasses may be so low that
they become as liquid as thin motor oil. Therefore, glasses, instead of having sharp melting points, soften gradually as the
temperature is raised (as the weaker chemical bonds, with their individual melting points,
break), until at high temperatures they finally become quite liquid. It is this gradual
softening over a range of several hundred degrees centigrade which makes it convenient to
describe glasses in terms of viscosities. |
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